problem related to outlook error : 4102

http://answers.microsoft.com/en-us/office/forum/office_2010-outlook/error-synchronizing-hotmail-account-with-outlook/13b52da9-ffbd-4e14-b859-3df04c1ed355

Removing and re-adding the account as suggested by Brian will help to fix the issue, for detailed information on how it can be done check the steps below.

1)    Remove the Hotmail account from Outlook. Refer to the link below for information on how to remove accounts from Outlook

           http://office.microsoft.com/en-us/outlook/HA012316341033.aspx 

2)    Delete the .OST file(s) associated with the Windows Live account

a.    Click on Start > All Programs > Accessories > Run

b.    Copy and paste the following text in the Open field and then press ‘Enter’:

          %userprofile%\Local Settings\Application Data\Microsoft\Outlook 

3)    Delete the .ost file(s) from the above location.

4)    Now configure the Hotmail account using Outlook connector in Outlook. Refer to the link below for information on how to add Windows Live account in Outlook.

           http://office.microsoft.com/en-us/outlook/HA102218231033.aspx

Remove an e-mail account

IN THE PROFILE THAT YOU ARE USING NOW

1.       On the Tools menu, click Account Settings.

The Account Settings command is missing

The Account Settings command is on the Tools menu in Office Outlook 2007 . If you are using an earlier version of Outlook, the following instructions do not apply. Use the Help that is included with that product. If the title bar of the program that you are using displays Outlook Express, then you are using a program that is not the same as Outlook. See the Help in Outlook Express for assistance.

2.       Select the account that you want to remove, and then click Remove.

3.       To confirm removal of the account, click Yes.